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Titles: ライジングボルテッカーズVSエクスプローラーズ！/The Rising Volt Tacklers VS The Explorers!
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In the center of Rakua, Pagogo releases the barrier it set up a 100 years ago... but then the Explorers suddenly appear so they can obtain the Rakulium. The decisive battle over the Rakulium now begins!

Summary:
In the center of Rakua, Pagogo releases the barrier it set up a 100 years ago... but then the Explorers suddenly appear, having been lying in wait for the barrier to get released so they can obtain the Rakulium...! The decisive battle in Rakua over the Rakulium now begins: Friede VS Spinel, Liko VS Onyx, Roy VS Sango and Dot VS Agate!!

Voice Cast:
Minori Suzuki: Liko
Megumi Hayashibara: Nyarote
Yuka Terasaki: Roy
Daiki Yamashita: Achigator
Yoshino Aoyama: Dot
Daisuke Namikawa: Welkamo
Taku Yashiro: Friede
Show Hayami: Gibeon
Makoto Furukawa: Spinel
Yuki Onodera: Onyx
Mimi Maihane: Agate
Kenta Miyake: Lizardon
Kei Shindo: Blacky
Tatsuki Kobe: Onigohri
Ayane Sakura: Onipurin (Sango's Scream Tail)
Arisa Shida: Charem
Ikue Ohtani: Captain Pikachu

Professor Friede's Pokémon Seminar:
Taku Yashiro: Friede
Ikue Ohtani: Captain Pikachu
Megumi Hayashibara: Nakanuchan
Daiki Yamashita: Ikkanezumi
Ayane Sakura: Ikkanezumi
Yoshino Aoyama: Ikkanezumi