Unreleased music:
DP 1 - 10:30, in the DVD version (Hikari asks to go and search for the four missing Pokémon and Nanakamado lets her. The music plays through the Eyecatch Break.)
Better to take the sample from DP 2, where it plays again at 11:02, in the DVD version, since it's longer (Hikari announces to Nanakamado that she'll search for Pikachu. The music overlaps the Eyecatch Break)

DP 4 - 10:32 (Nurse Joy registers Satoshi for the Shinou League with his Zukan.), very likely "2006-2010(DP)-M02-1", as there's a variant named as "2006-2010(DP)-M02-2", and they do share many of the instruments.
17:17 (The group and Naoshi hear the Pokémon's sounds in the forest.), probably "2006-2010(DP)-M02 B".

DP 11 - 09:52 (Hikari releases Pochama and Mimirol in the balcony, where she oversees Kotobuki City and tells the Pokémon to do their best in the next day's contest.) - The "B" version

DP 13 - 06:13 (Yukari states that they need to find higher ground in order to watch the Bird Pokémon.) - The "B" version